Conversion of cellulose to activated carbons for high-performance supercapacitors
¹LUT University, Energy Technology, Laboratory of Sustainable Energy Systems, Skinnarilankatu 34, FI53850 Lappeenranta, Finland
²University of Eastern Finland, Fine Particle and Aerosol Technology Laboratory, Yliopistonranta 1 C, FI70210 Kuopio, Finland
*Correspondence: ekaterina.sermyagina@lut.fi
Abstract:
Biomass-derived activated carbons are promising materials that can be used in various applications. Current work investigates the possibilities of the cellulose-derived activated carbons in substituting the commercial alternatives for the supercapacitors’ electrodes with high efficiency, stable performance and relatively low cost. Hydrothermal carbonization (HTC) followed by chemical activation with KOH is used to convert cellulose into highly porous activated carbons. The effect of HTC parameters on the material porosity development and electrochemical properties of the electrodes is evaluated with several variations of the residence time and the weight ratio between cellulose and water during the pretreatment. The analysis shows that intensification of the HTC process (longer residence time and higher water/cellulose ratio) results in increase of the surface area of both hydrochar samples and subsequent activated carbons: with the highest surface area for the sample produced after 2 h HTC treatment with water/cellulose ratio of 6/1 – 2,645 m2 g-1. As for the electrochemical analysis, the highest values of the specific capacitance are found for the samples produced from 2 h HTC treatment: 110.3 F g-1 (water/cellulose ratio of 3/1) and 102.5 F g-1 (water/cellulose ratio of 6/1). Additionally, it is noted that electrodes produced from the samples treated during 4 h have higher impedance at low operation frequency. The present study proves the possibility to substitute commercial activated carbons with cellulose-derived materials, the porosity of which can be tuned accordingly already during the pretreatment step.
Key words:
activated carbon, cellulose, electrodes, hydrothermal carbonization, supercapacitors